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ROS have crucial roles in normal physiological processes, such as through redox regulation of protein phosphorylation, ion channels, and transcription factors

Covalent/irreversible inhibitors target the redox/catalytic apparatus of TGR with almost no recognition elements that give affinity and selectivity for TGR over off-targets and the cellular redox apparatus resulting in undesirable cross-reactions and low specificity in vivo 25

Silica nanoparticles coated with polydopamine exhibit pH-sensitive mucus penetration, with diffusion rates approximately three times higher at pH 5.6 close to their isoelectric point than at more acidic (pH 3) or neutral (pH 7) conditions 184,185

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