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doi: 10.3390/molecules26195905 3 AharonA.SpectorP.AhmadR

This one is pretty straightforward

For ROS synthesis, only one statistically significant difference was observed, which occurred in the studies conducted on the effect of 2,4-D at a concentration of 10.00 mg/L

Anecdotal reports from topical application users mention occasional mild skin irritation at higher concentrations, but these observations lack systematic documentation