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The lifetime of the MLCT state is inversely related to the size of the alkyl ligand: 1 ns (methyl), 48 ps (ethyl), 32 ps (n-propyl), and 14 ps (adenosyl, if the MLCT state is present).Excitation at 400 nm opens a pathway for direct photohomolysis of the carbon-cobalt bond in methyl-, ethyl-, and n-propylcobalamin

doi: 10.1016/0014-4800(82)90082-X 147

To discern the molecular process engaged in the viral immune escape, it has been shown that infection with HPV16 inhibits the expression of TLR9 by E6 and E7, resulting in the downregulation of inflammatory cytokines like type-1 IFNs and inhibition of immune responses [76]